![]() ![]() This added complexity enables significant tuning of the optoelectronic properties of the NCs well beyond what would be feasible with the individual components in isolation. Core/shell heterostructures exhibit more complex size and compositional dependencies as the bandgap of the particle depends on both the position and relative offsets of the conduction and valence bands of the separate components ( Murray et al., 1993 Alivisatos, 1996 Peng and Peng, 2001 Reiss et al., 2009). Quantum confinement is easily observed in simple, single semiconductor nanocrystals (NCs): smaller cores are more quantum confined, resulting in an increase in the energy gap between the conduction and valence bands as observed through higher energy (bluer) photon emission following photoexcitation. Semiconductor quantum dots (QDs) are used to study the fundamental photophysics of quantum confined systems, as well as, for numerous applications in photovoltaics, solid state lighting, biomedical imaging, and biosensing ( Dennis et al., 2012b Chuang et al., 2014 Lan et al., 2014 Ten Cate et al., 2015 Kagan et al., 2016 Hong et al., 2017 Chandran et al., 2018 Kong L. Taken together, these InP-based heterostructures demonstrate the extent to which we are able to precisely tailor the material properties of core/shell particles using core/shell dimensions and composition as variables. Particles with thicker CdS(e) shells exhibit longer photoluminescence lifetimes, while little shell-thickness dependence is observed for the Zn-based shells. Specifically, Zn-based shells yield type-I structures that are color tuned through core size, while the Cd-based shells yield type-II particles that emit in the NIR regardless of the starting core size if several layers of CdS(e) have been successfully deposited. In this direct comparison of InP/ZnS, InP/ZnSe, InP/CdS, and InP/CdSe core/shell heterostructures, we clearly delineate the impact of core size, shell composition, and shell thickness on the resulting optical properties. Based on sizing data from transmission electron microscopy (TEM), it is observed that at the same particle diameter, average radiative lifetimes can differ as much as 20-fold across different shell compositions due to the relative positions of valence and conduction bands. Photoluminescence emission colors have been successfully tuned throughout the visible and into the near infrared (NIR) wavelength ranges for type-I and type-II heterostructures, respectively. The empirical results are compared to bandgap energy predictions made with effective mass modeling. The shell thickness and composition dependence of the bandgap for type-I and type-II heterostructures was observed by coating the InP core with ZnS, ZnSe, CdS, or CdSe through one to ten iterations of a successive ion layer adsorption and reaction (SILAR)-based shell deposition. In this paper, the dependence of the bandgap, photoluminescence emission, and exciton radiative lifetime of core/shell quantum dot heterostructures has been investigated using colloidal InP core nanocrystals with multiple diameters (1.5, 2.5, and 3.7 nm). The large bulk bandgap (1.35 eV) and Bohr radius (~10 nm) of InP semiconductor nanocrystals provides bandgap tunability over a wide spectral range, providing superior color tuning compared to that of CdSe quantum dots. 4Los Alamos National Laboratory, Materials Physics and Applications Division, Center for Integrated Nanotechnologies, Los Alamos, NM, United States.3Department of Biomedical Engineering, Boston University, Boston, MA, United States.2Theoretical Division, Los Alamos National Laboratory, Los Alamos, NM, United States.1Division of Materials Science and Engineering, Boston University, Boston, MA, United States.Reyhaneh Toufanian 1, Andrei Piryatinski 2, Andrew H. ![]()
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![]() As Polygon reported, the character had accounts on Soundcloud, Twitter, and Instagram before she was even officially tied to "League of Legends," although fans suspected that she was associated with the game long before it was confirmed. Seraphine's rollout started with social media. In the K/DA universe, she's an aspiring singer who worked a day job until K/DA discovered her, invited her to collaborate, and took her with them to perform in Shanghai (the site of this year's real "League of Legends" world championship). In the game, she's an idol who can hear the souls of others and uses her voice to try and heal the rift between her home city of Piltover and rival city Zaun, from which her parents hail. K/DA September 2, 2020Īhri, a popular nine-tailed fox mage in the game, is K/DA's leader, co-founder, and main vocalist.Ī post shared by Seraphine on at 8:42pm PDT at 8:42pm PDT While Akali is a rogue assassin in the game, K/DA Akali is the group's main rapper. These four characters are the static members of K/DA, and the group's identity revolves around them rather than the real-life collaborators who lend their voices to the project. ![]() However, the members of K/DA are alternate versions of their "League of Legends" characters, and while they bear some similarity to their in-game counterparts, they don't share the same lore. The group is comprised of 4 'League of Legends' characters with their own K/DA loreįour characters - or champions, as they're referred to in the game - from "League of Legends" make up the four members of K/DA. Here's a rundown of the group, from their 2018 origins to current activities and collaboration with Seraphine. K/DA's first EP, "ALL OUT," dropped on November 6, featuring five songs and a full slate of collaborators ranging from seasoned K-pop songwriter Bekuh Boom to pop artist Kim Petras to Chinese artist Lexie Liu. In 2020, the group has become more than a one-off project. Throw newcomer Seraphine, a new "League" character who has her own social media presence and featured on the recent K/DA EP, into the mix, and things can become even more confusing. Still, for the uninitiated there are a lot of levels to K/DA's existence: the members are virtual and based on "League of Legends" characters, but they're voiced by real-life artists who "collaborate" with the members on music. Their music and style are heavily K-pop influenced with plenty of modern pop flavor, and the animated music videos that accompany some of their releases are lush and intricate. You don't need to be a "League of Legends" player to enjoy the group's content. In 2020, they're coming back with a full EP, new lore, and a new featured artist: Seraphine, a new "League of Legends" video game champion and virtual influencer. ![]() Two years on the heels of the fictional group's first release, 2018's "POP/STARS," they're back with a five-track EP, "All Out," and a new roster of collaborators.Ĭomprised of versions of four "League of Legends" champions - Ahri, Akali, Evelynn, and Kai'sa - the group first debuted in 2018 in the lead up to the League of Legends World Championship Finals that were held that year in South Korea. ![]() K/DA, the multilingual, virtual girl group from Riot Games, has grown into a full musical force in 2020. Account icon An icon in the shape of a person's head and shoulders. ![]() ![]()
![]() ![]() It's very dramatic, and the final scene between Whitmore and his daughter is beautifully written. All of this leads to a big confrontation between Preacher and Dingo (the conflict with which the story began). 9.) Kitty decides to take the young girl under her wing, dress her up and show her (and her dad) what it's like to be an attractive young lady. 5.) The Preacher decides to conduct a "temperance" campaign and wipe out booze in Dodge 6.) Kitty (and later Wally and friends) decide to fight back 7.) The Preacher's daughter enlists the kindly Festus to assist in the campaign, creating additional conflict 8.) A huge street brawl breaks out at the preacher's meeting. 4.) Whitmore convinces the boy's parents that his recovery is due to divine intervention, but Doc Adams says it was a standard medical treatment issue (I thought the episode might develop this idea: spiritualism vs medicine, but it was dropped). 3.) Drunken rowdies in Dodge led by Wally (LQ Jones) accidentally cause a young boy to be run over. Dingo will continue to circulate as the plot develops. 2.) Young, violent miscreant named Dingo (John Saxon) puts the moves on her her father intervenes. Bennett, Christina Vantzau, Asher Woodworth, Tasos Grammatikos, Les Ateliers Claus, The Billy Ireland Cartoon Library, The Oglala Sioux Tribe, and the people of Livaniana, Embrosnerós, and Rodakino, Crete.Here they are: 1.) Rough-and-tough (self-appointed) Preacher (Whitmore) comes to Dodge with his lovely young daughter. ![]() ![]() Special thanks to Benjamin Bennett, William E. "Nowhere" and "Badlands" recorded at Les Ateliers Claus (Brussels, Belgium) and in Badlands National Park (South Dakota, USA), "Spectral Valley" recorded at The Schoolhouse (Brooklyn, USA), "Embrosnerós" recorded in Embrosnerós (Apokoronas, Crete, Greece) Bennett describes its creation as taking place “mostly during sunset hours, blanketed by waves of cicadas as sheep bells twinkled in the distance.” A micro-tuned DX7 radiates in the periphery while the guitar’s strings hang and reverberate like deepening shadows at dusk.Īll music composed, performed, recorded, and mixed by John Also Bennett Gestural breaths of lap steel shimmer in sparkling air, with echoes of both the dusty West and some forgotten paradise. Even outlier “Spectral Valley” – one of the few nods towards Bennett’s work in progressive kosmische trio Forma – unfolds with patient grandeur, rich swells of electronics gleaming in long golden arcs.Ĭlosing track “Embrosnerόs” (named for the verdant interior Cretan village where it was recorded) best embodies the album’s cinematic liminality, at the axis of barren and beatific. The use of extreme glissandos conjures a sense of windswept plains and winding canyons, primordial and unpopulated. Footsteps crunch across dry soil and rocky ravines, beneath skies stretching to the horizon. Opening with the desolate 15-minute “Nowhere,” Bennett’s playing is both glacial and geological, attuned to “the wonder and absolute emptiness” of the Badlands as “an infinite living sculpture.” Notes stretch, shift, and drift into vistas of twilit silence. ![]() This multi-layered generative process resulted in a collection as vast and bewildering as the terrain that inspired it: Out there in the middle of nowhere. The following year, upon relocating with his wife (Kranky composer Christina Vantzou) to the cliffside village of Livaniana on the island of Crete, Bennett discovered a method of translating his minimalist lap steel phrases into live MIDI information, which he then used to trigger different waveforms to extend the resonance of the instrument. Moved by the scale and complexity of the landscape – “remnants of an ancient seafloor mixed with the ash of a volcanic eruption, eroded over millennia and now resembling the tangled folds of earth’s brain” – he sculpted a series of stark, microtonal arrangements using a 1940’s Oahu lap steel guitar, a Yamaha SY77 multi-timbral synthesizer, and field recordings. Experimental musician John Also Bennett’s latest full-length emerged from a bicoastal pandemic road trip through the badlands of South Dakota. ![]() ![]() ![]() Using the Quick Hosting Setup describe above you can quickly get started building out your development environment. The returned invoice then passes through its service class (app/Services/Invoice) where various actions are performed.Ī event is then fired which notifies listeners in the application (app/Providers/EventServiceProvider) which perform non blocking sub tasksįinally the invoice is transformed (app/Transformers/) and returned as a response via Fractal. Here for example we are storing a new invoice, we pass the validated request along with a factory into the invoice repository where it is processed and saved. $invoice = $ this-> invoice_repo-> save( $request-> all(), InvoiceFactory:: create(auth()-> user()-> company()-> id, auth()-> user()-> id)) Įvent( new InvoiceWasCreated( $invoice, $invoice-> company, Ninja:: eventVars(auth()-> user() ? auth()-> user()-> id : null))) Public function store( StoreInvoiceRequest $request) Some of its core features include auto-billing and recurring invoices, real-time invoice PDF creation, and bulk invoicing. If successful, the request is then passed into the controller method where it is digested, here is an example: Invoice Ninja is a free open-source billing and invoicing solution that allows you to create and send invoices, set up vendors and track expenses, and manage projects for free. ![]() The request then passes into a Form Request (Type hinted in the controller methods) which is used to provide authorization and also validation of the request.Middleware processes the request initially inspecting the domain being requested + provides the authentication layer.The average API request follows this path into the application. The controller methods then describe all the entry points into each domain of the application, ie InvoiceController / QuoteController When inspecting functionality of the API, the best place to start would be in the routes/api.php file which describes all of the availabe API endpoints. The API and client portal have been developed using Laravel if you wish to contribute to this project familiarity with Laravel is essential. To setup your configuration if you did not load sample data. ![]() ![]() ![]() ![]() Johnson & Johnson Health and Wellness Solutions cares about your privacy and wants you to be familiar with how we collect, use, and disclose information. Please use these links to access supplemental Privacy Notices: PRIVACY STATEMENT FOR THE 7-MINUTE WORKOUT APP WEBSITE We may change this Cookie Policy as our use of cookies and similar technologies changes. If you have questions, comments, or concerns about this Cookie Policy or the information practices of this site, please use the contact information included in our Privacy Policy. Please be aware that we do not control the cookies or tracking technologies of other websites, and this Cookie Policy does not apply to those websites. This website contains links and references to other websites. 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![]() ![]() The Verdict: While “The Triumph of King Freak (A Crypt of Preservation and Superstition)” was the first single off of this album, the track that really encompasses the overall vibe has got to be “Shake Your Ass-Smoke Your Grass”. This track raises the question: can industrial-country be considered a thing? Although it is not totally out of left field, as it does remind one a little bit of “Well, Everybody’s F**king in a U.F.O” from The Electric Warlock Acid Witch Satanic Orgy Celebration Dispenser. Zombie has proclaimed himself a “hellbilly” and it appears he is taking this moniker to the next level. It has a country-ish sound reminiscent of Primus’ penchant for strange arrangements and old timey Americana. The Bad: One might say this is more weird than bad, but “18th Century Cannibals, Excitable Morlocks and a One-Way Ticket on the Ghost Train” has got to be the biggest deviation on the album from the Zombie norm (if there is such a thing). Since John 5 has released eight solo albums as a virtuoso guitarist, one can surmise that this evolution of the instrumental pieces in Zombie’s work are partly the guitarist’s influence. However, on his recent albums, these experiments with sound have morphed into some genuinely intriguing stand-alone instrumental songs. Zombie is known for his prominent use of samples and keyboards to add atmosphere to his songs, usually presented in the form of an intro to a track. Something that is worth noting is the evolution of the instrumental tracks on The Lunar Injection Kool Aid Eclipse Conspiracy, like the hypnotic “The Serenity of Witches” and the beautiful “The Much Talked of Metamorphosis”. Another is the single “The Eternal Struggles of the Howling Man”, which features some sick metal guitar riffs from the talented John 5. ![]() “Boom-Boom-Boom” is a standout with its churning groove evocative of “Pussy Liquor” from the House of 1000 Corpses soundtrack. ![]() Songs like “The Ballad of Sleezy Rider”, “The Satanic Rites of Blacula”, and “Shadow of the Cemetery Man” are catchy, heavy fun with a solid rhythm section and expert guitar work. The Good: In a world full of uncertainty, it really is comforting that Rob Zombie is still the man to see if you want to bang your head to songs about witches, graves, and monsters. The result is exactly what you would expect from Zombie: a well-produced and expertly written spooky, groovy, heavy, horror-inspired rock album with some added surprises. It also has the same producer as the previous album, the mysteriously named Zeuss (Queensrÿche, Hatebreed, Municipal Waste). The new effort continues with the same lineup as the previous two albums (2013’s Venomous Rat Regeneration Vendor and 2016’s The Electric Warlock Acid Witch Satanic Orgy Celebration Dispenser): Zombie on vocals, John 5 on guitar, Piggy D on bass, and Ginger Fish on drums. With an impressive 17 tracks, Zombie decided not to mess with a winning formula. The Lowdown: It has been five years since Rob Zombie’s last release, but The Lunar Injection Kool Aid Eclipse Conspiracy makes the wait worth it. ![]() ![]() ![]() Our car specialists work with all car manufacturers, from Lincoln to Porsche, so no matter what type of automobile you drive we are here to assist you. There are many cars on the road and different vehicles have different security systems and keys that need servicing. Regardless of what type of car key you have that needs replacing, our car key replacement experts are equipped to assist you. We work with ordinary car keys, as well as: Want your car key replaced? Our auto locksmith experts specialize in all types of car key replacements. If your lock is failing to function properly, or you want your auto locks replaced for whatever reason, our professional auto locksmith team is here to help. Carlock replacements are one of our car locksmith service areas of expertise. If your car lock is aged, damaged, or weathered to the point where you are concerned about the security of your vehicle, we can help you replace your car lock quickly and affordable. If you find yourself locked out of your vehicle, we can help you get back inside your vehicle and back on the road in no time. Thankfully, our team of mobile locksmiths for cars is certified to assist you in your car lockout situation. Whatever the reason you find yourself in a car lockout situation, you are not alone, in fact, thousands of people get locked out of their cars each day. Auto LockoutsĬar lockouts can happen for a variety of reasons, including lost or stolen keys and faulty car locks. That’s where our auto specialists can help. Instead, car owners need to hire local auto locksmiths to service their automotive locksmith need. All the complicated security technology means that when a crisis arises, it is much more difficult to resolve the issue on your own. While all these hi-tech security measures keep our cars more secure than ever, they do come with a downside. They’ve come up with things such as laser cut car keys, transponder keys, and car alarm systems which make vehicles much more difficult hotwire. Our experts are licensed for your protection and will charge you a fair locksmith price for their time.Īuto manufacturers have added security features that keep cars more secure than ever before. Locksmiths Pros representatives have the training to be certified for any auto locksmith job that needs doing. When you need a car locksmith, you want to call on someone who’s a trained professional and someone who understands your needs. ![]() Call us for a fast local car locksmith service in 30 minutes! LocksmithsPros Automotive Locksmith Services ![]() ![]() You can learn more about capturing on multiple channels here. As Airtool 2 receives packets from each wireless interface, it will merge them on the fly based on their timestamp to generate a single capture file. When you click “Start Capture,” Airtool 2 will connect to EASE, set each interface in monitor mode, configure the channel and channel width, and start a packet capture on all interfaces simultaneously. You can connect up to 8 USB adapters to the EASE VM. ![]() VirtualBox has a limit in the number of USB adapters the virtual machine can recognize. For each entry, specify the interface name and choose the channel and channel width.Add the same number of entries and select EASE as the sensor in all of them.Connect one external adapter per channel and choose “Multi-Source Capture” from the Airtool menu.If you want to do a capture on multiple channels: To use EASE with Airtool 2, we recommend Airtool 2.1.1 or higher.Īfter connecting the first adapter, Airtool 2 will automatically add EASE as a remote sensor and make it available as a capture option.įor capturing on a single channel, choose “EASE” from the Airtool menu and then specify the interface name (e.g., wlan0), channel, and channel width. The first adapter that you connect to EASE will be named wlan0, the second adapter wan1, the third adapter wlan2, and so on. Once installed, follow the steps to attach one or more multiple adapters to the EASE virtual machine. Using EASE with Airtool 2 is very easy, just download and install EASE following the instructions here. To learn how to install and use EASE with WiFi Explorer Pro, please read Using external USB Wi-Fi adapters with WiFi Explorer Pro. Using a USB hub, for example, you can attach multiple compatible Wi-Fi adapters to EASE and use them for Wi-Fi scanning and capturing using WiFi Explorer Pro and Airtool 2. You can imagine EASE as having a WLAN Pi or Raspberry Pi running on your local system. Although virtualization for some ARM-based Linux systems is possible in Apple silicon Macs, tools such as VirtualBox, which we use to manage EASE, are not supported in Apple silicon Macs. And as long as you use a compatible USB Wi-Fi adapter, you don’t need any additional configuration.ĮASE is only available in Macs with an Intel processor. ![]() The base EASE image includes the necessary wireless drivers to support Wi-Fi scanning and capturing. When you attach an external adapter to the EASE virtual machine, EASE automatically exposes it to WiFi Explorer Pro and Airtool 2. However, because we can’t use external adapters natively as we do with the Mac’s built-in Wi-Fi adapter, we need the External Adapter Support Environment, EASE.ĮASE is a custom, lightweight Debian virtual machine that allows WiFi Explorer Pro and Airtool 2 to use external USB Wi-Fi adapters on your Mac. If you don’t have a remote sensor, you can still do packet captures on one or more channels using external USB Wi-Fi adapters. But what if you don’t have a remote sensor? In a recent blog, we showed you how you could do Wi-Fi packet captures on multiple channels simultaneously using Airtool 2 and remote sensors such as the WLAN Pi or a Raspberry Pi 4. ![]() |
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